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Anion exchange membranes (AEMs) have emerged as a promising technology for water electrolysis in hydrogen production since they offer significant cost reduction in choices of electrocatalysts and bipolar plates. However, AEMs satisfying multiple requirements of high ionic conductivity, good chemical stability, robust mechanical properties, scalable synthesis, and low manufacturing costs are rare. Herein, we introduce quaternary ammonium functionalized cyclic olefin copolymers (COCs) as a new class of chemically stable and low-cost AEM materials. To further enhance the mechanical robustness, we prepared reinforced composite AEMs by impregnating the ionically functionalized COC into a mechanically robust matrix. The resulting reinforced composite membranemore » exhibits a high hydroxide conductivity of 127 mS cm⁻¹ and excellent mechanical strength. In water electrolyzers, the MEA demonstrated outstanding performance, achieving a current density of 2.24 A cm⁻² at 1.8 V, attributable to high conductivity, enhanced mechanical properties, and good alkaline stability of the composite membrane. These results indicate that the COC-based AEMs demonstrate good potential for application in AEM electrolyzers.« less

The increasing demand for efficient and sustainable hydrogen production has driven significant advancements in water electrolysis technologies. Among these, liquid alkaline water electrolysis (LAWE) stands out for its cost-effectiveness and scalability. This manuscript establishes best practices and standardized testing procedures for single-cell LAWE, focusing on the use of nickel foam as both anode and cathode substrates, while incorporating catalysts such as nickel-iron layered double hydroxide (NiFe-LDH) as the anode material and nickel-molybdenum on carbon (NiMo/C) as the cathode material. By providing detailed guidelines on material preparation, cell assembly, and performance evaluation, this work offers a comprehensive framework to improve reproducibilitymore » and ensure consistency. The results demonstrate that applying these best practices minimizes variability across different laboratories and experimental setups, laying the groundwork for more robust comparisons and accelerating progress in LAWE research.« less

Anode ionomers of alkaline membrane fuel cells (AMFCs) play a critical role in hydrogen and water transport thus affecting cell performance and durability. Here, we modified a quaternized poly(biphenyl alkylene) ionomer with two chemical structural variations to increase hydrogen access to the AMFC anode: first, we introduced the symmetric dimethyl groups in the polymer backbone to increase polymer fractional free volume. Second, we replaced hydroxide-conducting alkyl trimethylammonium with alkyl triethylammonium to reduce cation–hydroxide–water co-adsorption on the hydrogen oxidation catalyst to increase hydrogen access to the co-adsorbed layer. Furthermore, we compared the performance benefits of the two structural variations through operatingmore » AMFCs under H₂/O₂ conditions. The membrane electrode assembly employing the modified poly(biphenyl alkylene) ionomer at the anode exhibited >1500 mW cm^-2 peak power density at 80 °C with stable short-term durability (>100 h) under a constant current density of 0.6 A cm^-2. This study provides an essential insight into designing anode ionomer of highly performing AMFCs.« less

The durability of alkaline anion exchange membrane fuel cells (AEMFCs) is a critical requirement for implementing this technology in cost-effective energy conversion. However, the lifetime of current AEMFCs is short, ca. < 1,000 h and the cause of the performance loss over time is poorly understood. Here, we investigate the origin of AEMFC unrecoverable performance loss. We diagnosed the recoverable performance loss induced by carbonation and anode flooding during an extended-term test with transient operating conditions. Multiple extended-term tests under current densities and the electrochemical and analytical analyses suggest that the most prominent permanent performance loss of AEMFCs occurs bymore » phenol formation as a result of electrochemical phenyl oxidation of cathode ionomeric binder. The produced phenol is acidic and neutralizes the quaternary ammonium group to lower the local pH. Finally, the impact of this degradation pathway is discussed to explain the reported lifetime performance of current AEMFCs.« less